144899-38-7

Upstream product

• 75-16-1 methylmagnesium bromide 
• 5619-07-8 methyl 2-amino-3-phenylpropanoate hydrochloride 
• 150-30-1 Phenylalanine 
• 917-64-6 methyl magnesium iodide 

Downstream Products

• 126376-21-4 DL-3-Benzyl-2,2-dimethylaziridine 
• 352438-06-3 4-benzyl-5,5-dimethyloxazolidin-2-one 
• 860312-72-7 tert-butyl (3-hydroxy-3-methyl-1-phenylbutan-2-yl)carbamate 
• 126421-30-5 DL-3-Azido-3-methyl-1-phenyl-2-butanamine 
• 126376-27-0 DL-3-Methyl-1-phenyl-2,3-butanediamine 

Relevant academic research and scientific papers

Controllable Intramolecular Unactivated C(sp3)-H Amination and Oxygenation of Carbamates

Dual catalyst-controlled intramolecular unactivated C(sp3)-H amination and oxygenation of carbamates merging visible-light photocatalysis and earth-abundant transition metal catalysis have been reported. Useful amino alcohol and diol derivatives could be selectively obtained from readily available tertiary alcohol derivatives. The possible mechanisms have been proposed via a 1,5-HAT process followed by Lewis acid-controlled cyclization. The nickel and zinc catalysts inhibit the formation of oxygenation and amination products, respectively. An interesting phenomenon of chirality transfer is also observed.

Synthesis and Antitumor Activity of Pt(II) Complexes of Benzyl-1,2-diaminoethane Ligands

Twelve new diamine ligands are synthesized and characterized in which a benzyl group and another vicinal substituent or a benzyl group, a 4-Cl-benzyl group, and a 4-MeO-benzyl group, respectively, and two other geminal substituents are attached to the 1,2