144969-05-1Relevant articles and documents
Sulfur ylide mediated three-component aziridination and epoxidation reactions using vinyl sulfonium salts
Kokotos, Christoforos G.,McGarrigle, Eoghan M.,Aggarwal, Varinder K.
, p. 2191 - 2195 (2008)
Coupling of diphenylvinyl sulfonium triflate with nucleophiles and either aldehydes or imines gives epoxides and aziridines, respectively, in a three-component reaction. cis-Aziridines could be formed in good diastereomeric ratio, and the selectivity was correlated to the reactivity of the imine. This represents the first study of cis/trans selectivity in the reactions of imines with non-stabilized sulfur ylides. Georg Thieme Verlag Stuttgart.
Catalytic, Enantioselective Syn-Oxyamination of Alkenes
Denmark, Scott E.,Hemric, Brett N.,Mumford, Emily M.
supporting information, p. 13408 - 13417 (2021/09/03)
The chemo-, regio-, diastereo-, and enantioselective 1,2-oxyamination of alkenes using selenium(II/IV) catalysis with a chiral diselenide catalyst is reported. This method uses N-tosylamides to generate oxazoline products that are useful both as protected
Studies of Regio- and Stereoselectivity in Some Nucleophilic Ring Opening Reactions of N-Tosyl-3-phenyl-2-aziridinemethanols and Derivatives
Tanner, David,Gautun, Odd R.
, p. 8279 - 8288 (2007/10/02)
A study has been made of the regio- and stereoselectivity of the ring opening reactions of the 3-aryl substituted aziridines 1 and 2.The regiochemical outcome is apparently decided by a balance of electronic activation at C-3 by the phenyl group and the c
