165754-26-7

Basic information

• Product Name: Benzene, [3-(phenylmethoxy)-1-propenyl]-
• CAS NO: 165754-26-7
• Molecular Formula: C16H16O
• Molecular Weight: 224.302
• Mol File: 165754-26-7.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzene, [3-(phenylmethoxy)-1-propenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [3-(phenylmethoxy)-1-propenyl]-(165754-26-7)
• EPA Substance Registry System: Benzene, [3-(phenylmethoxy)-1-propenyl]-(165754-26-7)

Safety Data

• Hazardous Substances Data: 165754-26-7(Hazardous Substances Data)

Upstream product

• 104-54-1 3-Phenylpropenol 
• 100-51-6 benzyl alcohol 
• 85217-69-2 cinnamyl methyl carbonate 
• 14371-10-9 (E)-3-phenylpropenal 
• 144479-03-8 1-phenyl-3-benzyloxy-1-propyne 
• 673-32-5 1-Phenylprop-1-yne 
• 124517-47-1 cinnamyl tert-butyl carbonate 
• 100-39-0 benzyl bromide 
• 100-44-7 benzyl chloride 

Downstream Products

• 1033320-99-8 C₁₆H₁₆⁽²⁾H₂O 
• 7310-74-9 triphenylcinnamylphosphonium bromide 
• 103-41-3 benzy cinnamate 
• 122-97-4 3-Phenyl-1-propanol 
• 330825-70-2 (S)-1-phenyl-3-benzyloxy-1-(trichlorosilyl)propane 
• 70770-06-8 1-benzyloxy-3-phenylpropane 
• 101306-27-8 2-((benzyloxy)methyl)-3-phenyloxirane 

Relevant articles and documents

Ternary Catalysis Enabled Three-Component Asymmetric Allylic Alkylation as a Concise Track to Chiral α,α-Disubstituted Ketones

Multicomponent reactions that involve interception of onium ylides through Aldol, Mannich, and Michael addition with corresponding bench-stable acceptors have demonstrated broad applications in synthetic chemistry. However, because of the high reactivity and transient survival of these in situ generated intermediates, the substitution-type interception process, especially the asymmetric catalytic version, remains hitherto unknown. Herein, a three-component asymmetric allylation of α-diazo carbonyl compounds with alcohols and allyl carbonates is disclosed by employing a ternary cooperative catalysis of achiral Pd-complex, Rh2(OAc)4, and chiral phosphoric acid CPA. This method represents the first example of three-component asymmetric allylic alkylation through an SN1-type trapping process, which involves a convergent assembly of two active intermediates, Pd-allyl species, and enol derived from onium ylides, providing an expeditious access to chiral α,α-disubstituted ketones in good to high yields with high to excellent enantioselectivity. Combined experimental and computational studies have shed light on the mechanism of this novel three-component reaction, including the critical role of Xantphos ligand and the origin of enantioselectivity.

Electrochemical properties and reactions of organoboronic acid esters containing unsaturated bonds at their α-position

Electrochemical analyses of 2-(cynnamyl)boronic acid pinacol ester and (3-phenyl-2-propynyl)boronic acid pinacol ester, and their trimethylsilyl analogues as well as their parent compounds were comparatively studied by cyclic voltammetry measurements. We

Organohalide-catalyzed dehydrative O-alkylation between alcohols: A facile etherification method for aliphatic ether synthesis

Organohalides are found to be effective catalysts for dehydrative O-alkylation reactions between alcohols, providing selective, practical, green, and easily scalable homo- and cross-etherification methods for the preparation of useful symmetrical and unsymmetrical aliphatic ethers from the readily available alcohols. Mechanistic studies revealed that organohalides are regenerated as reactive intermediates and recycled to catalyze the reactions.