145107-32-0Relevant academic research and scientific papers
A Convenient Preparation of 2,4,6-Trisubstituted 1,3,5-Triselenanes by Treating Aldehydes of Their Acetals with 2,2,4,4,6,6-Hexamethyl-1,3,5-triselena-2,4,6-tristannacyclohexane in the Presence of BF3*OEt2 and AlCl3
Shimada, Kazuaki,Okuse, Satoshi,Takikawa, Yuji
, p. 2848 - 2850 (1992)
A convenient preparation of 2,4,6-trisubstituted 1,3,5-triselenanes was achieved by the treatment of aldehydes or their acetals with 2,2,4,4,6,6-hexamethyl-1,3,5-triselena-2,4,6-tristannacyclohexane, (Me2SnSe)3, in the presence of BF3*OEt2 and AlCl3.
Stannic chloride-induced unsymmetrical C-se bond cleavage of bis(N,N-dimethylcarbamoylseleno)methanes: Novel generation of selenoaldehydes
Gong, Yaling,Shimada, Kazuaki,Nakamura, Hidenori,Fujiyama, Masamichi,Kodama, Akihiro,Otsuki, Miyuki,Matsumoto, Rei,Aoyagi, Shigenobu,Takikawa, Yuji
, p. 125 - 135 (2007/10/03)
Treatment of bis(N,N-dimethylcarbamoylseleno)methanes with SnCl4 afforded β-1,3,5-triselenanes in moderate to high yields, and the key intermediates of the reactions, i.e., acylselonium ions and selenoaldehydes, were successfully trapped by usi
Novel generation of selenoaldehydes through stannic chloride-induced unsymmetrical C-Se bond cleavage of bis(N,N-dimethylcarbamoylseleno)methanes
Shimada, Kazuaki,Gong, Yaling,Nakamura, Hidenori,Matsumoto, Rei,Aoyagi, Shigenobu,Takikawa, Yuji
, p. 3775 - 3778 (2007/10/03)
Treatment of a benzene or a CH2Cl2 solution of bis(N,N-dimethylcarbamoylseleno)methanes with SnCl4 afforded β-1,3,5-triselenanes, and the key intermediates, acylselonium ions and selenoaldehydes, were successfully trapped
