1451497-61-2Relevant academic research and scientific papers
Preparation of vinyl silyl ethers and disiloxanes via the silyl-heck reaction of silyl ditriflates
Martin, Sara E. S.,Watson, Donald A.
supporting information, p. 13330 - 13333 (2013/09/24)
Vinyl silyl ethers and disiloxanes can now be prepared from aryl-substituted alkenes and related substrates using a silyl-Heck reaction. The reaction employs a commercially available catalyst system and mild conditions. This work represents a highly practical means of accessing diverse classes of vinyl silyl ether substrates in an efficient and direct manner with complete regiomeric and geometric selectivity.
