145175-64-0Relevant articles and documents
Vanadium-substituted MCM-41 zeolites as catalysts for oxidation of alkanes with peroxides
Neumann, Ronny,Khenkin, Alexander M.
, p. 2643 - 2644 (1996)
Alkanes are oxidized selectively to ketones using V-MCM-41 with isobutyraldehyde/dioxygen as the preferred oxidant in terms of product selectivity and catalyst stability and recycle.
Ruthenium colloids: A new catalyst for alkane oxidation by tBHP in a biphasic water-organic phase system
Launay, Franck,Roucoux, Alain,Patin, Henri
, p. 1353 - 1356 (2007/10/03)
Efficient and highly selective conversion of cyclooctane into cyclooctanone is obtained under pure biphasic conditions through t-butylhydroperoxide activation by the in situ formation of colloidal ruthenium species arising from RuCl3, 3H2O. Model extension experiments to other cycloalkanes are also discussed.
A putative monooxygenase mimic which functions via well-disguised free radical chemistry
MacFaul, Philip A.,Ingold,Wayner,Que Jr., Lawrence
, p. 10594 - 10598 (2007/10/03)
The hydroxylation of cycloalkanes at 25°C by the syringe pump addition of tert-alkyl hydroperoxides (10 and 1 equiv based on catalyst) to deoxygenated acetonitrile containing cycloalkanes (0.64 M) and 0.61 mM of the catalyst, [Fem(III)2O(TPA)2(H2O)2]4+, is demonstrated to be a reaction which involves freely diffusing cycloalkyl radicals, i.e., free alkyl radicals.
