145207-45-0

Basic information

• Product Name: (R)-3-(4-Methoxy-phenyl)-4,6-dioxo-2-phenyl-5-[1-phenyl-meth-(Z)-ylidene]-[1,3]oxazinane-2-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester
• CAS NO: 145207-45-0
• Molecular Weight: 567.682
• Mol File: 145207-45-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-3-(4-Methoxy-phenyl)-4,6-dioxo-2-phenyl-5-[1-phenyl-meth-(Z)-ylidene]-[1,3]oxazinane-2-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-3-(4-Methoxy-phenyl)-4,6-dioxo-2-phenyl-5-[1-phenyl-meth-(Z)-ylidene]-[1,3]oxazinane-2-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester(145207-45-0)
• EPA Substance Registry System: (R)-3-(4-Methoxy-phenyl)-4,6-dioxo-2-phenyl-5-[1-phenyl-meth-(Z)-ylidene]-[1,3]oxazinane-2-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester(145207-45-0)

Safety Data

• Hazardous Substances Data: 145207-45-0(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 145207-50-7 (R)-3-(4-Methoxy-phenyl)-4,6-dioxo-2-phenyl-[1,3]oxazinane-2-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 145207-46-1 [(E)-4-Methoxy-phenylimino]-phenyl-acetic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 104-94-9 4-methoxy-aniline 
• 20229-41-8 l-menthyl phenylglyoxylate 

Downstream Products

• 16460-78-9 (S)-3-phenylvaleric acid 
• 150917-79-6 (2R,5R)-7,7-Diethoxy-3-(4-methoxy-phenyl)-4-oxo-2,5-diphenyl-3,4,6,7-tetrahydro-2H,5H-pyrano[3,2-e][1,3]oxazine-2-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 140863-09-8 (R)-3-phenylglutaric acid monoethyl ester 
• 140863-10-1 (R)-4-(4-Methoxy-phenylcarbamoyl)-3-phenyl-butyric acid ethyl ester 
• 145207-49-4 (S)-3-(4-Methoxy-phenyl)-4,6-dioxo-2-phenyl-5-((S)-1-phenyl-propyl)-[1,3]oxazinane-2-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 95592-75-9 3-phenyl-pentanedioic acid monomethyl ester 

Relevant articles and documents

l-Menthyl (2S)-2-phenyl-3-(p-anisyl)-(5Z)-benzylidene-4,6-dioxo-1,3-oxazine-2-ca rboxylate: A new chiral heterodiene and Michael acceptor

The title homochiral oxazinedione has been synthesized from l-menthyl phenylglyoxylate in three steps and found to exhibit high diastereofacial selectivity (≥99%) when used as heterodiene and Michael acceptor.