1452783-14-0Relevant articles and documents
Synthesis and characterization of conjugated Dawson-type polyoxometalate-porphyrin copolymers
Azcarate, Iban,Ahmed, Iftikhar,Farha, Rana,Goldmann, Michel,Wang, Xiaoxia,Xu, Hualong,Hasenknopf, Bernold,Lac?te, Emmanuel.,Ruhlmann, Laurent
, p. 12688 - 12698 (2013)
Hybrid polyoxometalate-porphyrin copolymeric films were obtained by the electro-oxidation of zinc octaethylporphyrin (ZnOEP) in the presence of a Dawson type polyoxophosphovanadotungstate bearing two pyridyl groups (POM(py) 2). The synthesis of a series of POM(py)2 consisting of [P2W15V3O62]9- functionalized with diol-amide or triol moieties, as well as the characterization of the copolymers are presented.