1452876-71-9Relevant academic research and scientific papers
Copper-catalyzed aromatic C-H bond cyanation by C-CN bond cleavage of inert acetonitrile
Kou, Xuezhen,Zhao, Mengdi,Qiao, Xixue,Zhu, Yamin,Tong, Xiaofeng,Shen, Zengming
, p. 16880 - 16886 (2013)
Cut and paste! A Cu-catalyzed aromatic C-H cyanation with acetonitrile as the nitrile source by C-CN cleavage has been developed (see scheme; TMEDA=N,N,N′,N′-tetramethylethylenediamine). The reaction is catalytic in copper, and it is found that using (Me
Aerobic Direct C(sp2)-H Hydroxylation of 2-Arylpyridines by Palladium Catalysis Induced with Aldehyde Auto-Oxidation
Das, Prasenjit,Saha, Debajyoti,Saha, Dibyajyoti,Guin, Joyram
, p. 6050 - 6054 (2016/09/09)
Herein we present a Pd-catalyzed direct C-H hydroxylation of 2-arylpyridines using molecular oxygen (O2) as the sole oxidant. The key aspects of the method include: (a) the activation of molecular oxygen with a nontoxic and inexpensive aldehyde
PdCl2 and N-hydroxyphthalimide co-catalyzed c sp 2 -H hydroxylation by dioxygen activation
Yan, Yuepeng,Feng, Peng,Zheng, Qing-Zhong,Liang, Yu-Feng,Lu, Jing-Fen,Cui, Yuxin,Jiao, Ning
supporting information, p. 5827 - 5831 (2013/06/27)
Rad transition: The combination of transition-metal-catalyzed C-H activation and a NHPI-initiated radical process is essential for the title transformation. The neutral conditions and the ideal oxidant, molecular oxygen, make this hydroxylation environmen
