Chemistry - A European Journal p. 16880 - 16886 (2013)
Update date:2022-08-04
Topics: C-H bond activation Acetonitrile Organic chemistry Copper catalyst Hydrogen Atom Abstraction
Kou, Xuezhen
Zhao, Mengdi
Qiao, Xixue
Zhu, Yamin
Tong, Xiaofeng
Shen, Zengming
Cut and paste! A Cu-catalyzed aromatic C-H cyanation with acetonitrile as the nitrile source by C-CN cleavage has been developed (see scheme; TMEDA=N,N,N′,N′-tetramethylethylenediamine). The reaction is catalytic in copper, and it is found that using (Me<
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