1452892-54-4

Basic information

• Product Name: 1-(2-vinylphenyl)prop-2-en-1-ol
• Synonyms: 1-(2-vinylphenyl)prop-2-en-1-ol
• CAS NO: 1452892-54-4
• Molecular Weight: 160.216
• Mol File: 1452892-54-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(2-vinylphenyl)prop-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-vinylphenyl)prop-2-en-1-ol(1452892-54-4)
• EPA Substance Registry System: 1-(2-vinylphenyl)prop-2-en-1-ol(1452892-54-4)

Safety Data

• Hazardous Substances Data: 1452892-54-4(Hazardous Substances Data)

Upstream product

• 2039-88-5 2-bromostyrene 
• 107-02-8 acrolein 
• 6630-33-7 ortho-bromobenzaldehyde 
• 28272-96-0 2-vinylbenzaldehyde 
• 1826-67-1 vinyl magnesium bromide 

Downstream Products

• 61463-21-6 3-Hydroxyindene 
• 1452892-55-5 C₁₃H₁₁Cl₃O₂ 

Relevant articles and documents

Intramolecular Crossed [2+2] Photocycloaddition through Visible Light-Induced Energy Transfer

Herein, we present the intramolecular [2+2] cycloadditions of dienones promoted through sensitization, using a polypyridyl iridium(III) catalyst, to form bridged cyclobutanes. In contrast to previous examples of straight [2+2] cycloadditions, these efficient crossed additions were achieved under irradiation with visible light. The reactions delivered desired bridged benzobicycloheptanone products with excellent regioselectivity in high yields (up to 96%). This process is superior to previous syntheses of benzobicyclo[3.1.1]heptanones, which are readily converted to B-norbenzomorphan analogues of biological significance. Electrochemical, computational, and spectroscopic studies substantiated the mechanism of triplet energy transfer and explained the unusual regiocontrol.

New synthesis of A-ring aromatic strigolactone analogues and their evaluation as plant hormones in pea (pisum sativum)

A new general access to A-ring aromatic strigolactones, a new class of plant hormones, has been developed. The key transformations include in sequence ring-closing metathesis, enzymatic kinetic resolution and a radical cyclization with atom transfer to install the tricyclic ABC-ring system. The activity as plant hormones for the inhibition of shoot branching in pea of various analogues synthesized by this strategy is reported. Inhibiting shoot branching: A new general access to A-ring aromatic strigolactones (see scheme), a new class of plant hormones, has been developed. The biological activity of various analogues synthesized by this strategy for inhibiting bud outgrowth in pea was evaluated. Copyright