1453119-60-2Relevant academic research and scientific papers
Rhenium-catalyzed acceptorless dehydrogenative coupling via dual activation of alcohols and carbonyl compounds
Jin, Hongming,Xie, Jin,Pan, Changduo,Zhu, Zhengbo,Cheng, Yixiang,Zhu, Chengjian
, p. 2195 - 2198 (2013/10/22)
The rhenium hetaphydride complex was found to be a versatile, homogeneous catalyst for dehydrogenative functionalization of alcohol. The dehydrogenative C-C coupling of alcohols and carbonyl compounds was carried out in the absence of base and hydrogen acceptors to afford a series of α,β-unsaturated carbonyl compounds. A possible dual activation pathway was proposed by mechanistic investigations.
Palladium/copper-catalyzed oxidative C-H alkenylation/N-dealkylative carbonylation of tertiary anilines
Shi, Renyi,Lu, Lijun,Zhang, Hua,Chen, Borui,Sha, Yuchen,Liu, Chao,Lei, Aiwen
supporting information, p. 10582 - 10585 (2013/10/21)
C-H/C-N activation: The first palladium/copper-catalyzed aerobic oxidative C-H alkenylation/N-dealkylative carbonylation of tertiary anilines has been developed. Various functional groups were tolerated and acrylic ester could also be suitable substrates. This transformation provided efficient and straightforward synthesis of biologically active 3-methyleneindolin-2-one derivatives from cheap and simple substrates. Copyright
