14536-19-7

Basic information

• Product Name: ZIRCONIUM OXALATE
• Synonyms: ZIRCONYL OXALATE;ZIRCONIUM OXALATE;oxalic acid, zirconium salt;Ethanedioic acid/zirconium,(1:x) salt
• CAS NO: 14536-19-7
• Molecular Formula: 2C₂O₄*Zr
• Molecular Weight: 267.26
• EINECS: 238-571-5
• Mol File: 14536-19-7.mol
• Article Data: 6

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: ZIRCONIUM OXALATE(CAS DataBase Reference)
• NIST Chemistry Reference: ZIRCONIUM OXALATE(14536-19-7)
• EPA Substance Registry System: ZIRCONIUM OXALATE(14536-19-7)

Safety Data

• Hazardous Substances Data: 14536-19-7(Hazardous Substances Data)

Usage

General Description

Zirconium oxalate is a chemical compound with the formula Zr(C2O4)2. It is a white crystalline powder that is insoluble in water and most organic solvents. Zirconium oxalate is commonly used as a precursor in the production of zirconium dioxide and other zirconium compounds. It is also utilized in the fabrication of ceramic and glass materials. Additionally, zirconium oxalate has been studied for its potential use in catalysis and as a corrosion inhibitor due to its high chemical stability and resistance to harsh environmental conditions. Overall, zirconium oxalate plays a crucial role in various industrial applications and scientific research.

InChI:InChI=1/C2H2O4.Zr/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2

Upstream product

• 144-62-7 oxalic acid 
• 7699-43-6 zirconyl chloride 
• 10026-11-6 zirconium(IV) chloride 

Downstream Products

• 7440-67-7 zirconium(IV) oxide 

Relevant articles and documents

Effect of organic acids precursors on the morphology and size of ZrO2 nanoparticles for photocatalytic degradation of Orange G dye from aqueous solutions

Zirconium oxide nanoparticles were prepared by precipitation from different organic acid precursors (oxalic, tartaric, citric, succinic, malic, maleic and malonic) and ignition at 750 °C. The as-prepared samples were characterized by XRD, FT-IR, UV–Vis an

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On the activity of ZrO2 prepared by different methods

Zirconia samples with different structures (monoclinic, tetragonal or a mixture of the two) was prepared by different methodologies, including a novel procedure involving the precipitation of an oxalate precursor and the formation of pure tetragonal ZrO2. The different precursors obtained by varying the preparative procedure (ex oxychloride, ex oxalate, and ex gel) were studied by means of differential thermal analysis and thermogravimetric analysis under air and under N2, while the final oxides were characterized by BET, porosimetry and XRD analysis. The surface acid-base properties of the different oxides were assessed via the catalytic decomposition isopropanol. A prevalence of acid sites found for the ex-oxalate ZrO2 seems to justify the different mechanism of chain growth observed in the carbonylation of methanol with CO/H2 mixtures in the presence of Rh.

Nanocrystalline oxalate/carbonate precursors of Ce and Zr and their decompositions to CeO2 and ZrO2 nanoparticles

The oxalate and carbonate precursors of cerium and zirconium have been prepared using reverse micelles as nanoreactors. Cerium oxalate precursor on thermal decomposition leads to a mixture of nanorods and nanoparticles of cerium oxide (nanoparticles of 10 nm and nanorods with 7 nm diameter and 30 nm length). Cerium oxide with crystallite size of 10 nm was obtained from cerium carbonate precursor. Monodispersed nanoparticles of zirconia with an average size of 3-5 and 12 nm were obtained from the oxalate and carbonate precursor, respectively. Detailed dielectric properties of sintered discs of nanocrystalline ceria and zirconia have been studied with variation of frequency and temperature.