145369-05-7Relevant academic research and scientific papers
Branched-Chain Carbohydrate Lactones from a Samarium(II) Iodide-Promoted Serial Deoxygenation-Carbonyl Addition Reaction
Enholm, Eric J.,Jiang, Shujun,Abboud, Khalil
, p. 4061 - 4069 (2007/10/02)
A new deoxygenation-carbonyl addition reaction mediated by samarium(II) iodide (SmI2) in THF/HMPA was examined with carbohydrate lactones and several substrates containing an α-alkoxy carboxylic ester.In a single reaction, these compounds were deoxygenate
BRANCHED CHAIN CARBOHYDRATE LACTONES FROM A TANDEM SmI2 DEHYDROGENATION-CARBONYL ADDITION REACTION
Enholm, Eric J.,Jiang, Shujun
, p. 2247 - 2252 (2007/10/02)
Treatment of a carbohydrate lactone with a ketone in the presence of SmI2-HMPA produces a deoxygenation/carbonyl addition reaction to afford new C2-branched chain carbohydrates.
CRYSTALLINE FURANOSE DERIVATIVES OF 3-DEOXY-D-arabino-HEXOSE:CONFORMATIONAL STUDIES BY N.M.R. SPECTROSCOPY
Mortier, Cecile du,Lederkremer, Rosa M. de
, p. 47 - 54 (2007/10/02)
Debenzoylation of 2,4,6-tri-O-benzoyl-3-deoxy-D-arabino-hexono-1,5-lactone(1) followed by heating in vacuo and rebenzoylation afforded 2,5,6-tri-O-benzoyl-3-deoxy-D-arabino-hexono-1,4-lactone (2).Reduction of 2 with disiamylborane gave 2,5,6-tri-O-benzoyl
