145369-08-0Relevant academic research and scientific papers
HIGHLY STEREOSELECTIVE COUPLINGS OF CARBOHYDRATE LACTONES WITH TERPENE KETONES PROMOTED BY SmI2
Enholm, Eric J.,Jiang, Shujun
, p. 6069 - 6072 (1992)
Lactone 3-deoxycarbohydrates were reacted with samarium diiodide (SmI2) in THF/HMPA and the terpene ketones, (-)-menthone or (+)-dihydrocarvone; a serial reductive deoxygenation and an attendant carbonyl addition reaction afforded C2 branched sugars with
