1453859-74-9

Basic information

• Product Name: (Z)-1-p-tolylbut-2-en-1-one
• Synonyms: (Z)-1-p-tolylbut-2-en-1-one
• CAS NO: 1453859-74-9
• Molecular Weight: 160.216
• Mol File: 1453859-74-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-1-p-tolylbut-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-p-tolylbut-2-en-1-one(1453859-74-9)
• EPA Substance Registry System: (Z)-1-p-tolylbut-2-en-1-one(1453859-74-9)

Safety Data

• Hazardous Substances Data: 1453859-74-9(Hazardous Substances Data)

Upstream product

• 24165-63-7 1-p-tolyl-3-buten-1-ol 
• 130649-66-0 1-(4-Methylphenyl)-3-buten-1-one 
• 104-87-0 4-methyl-benzaldehyde 

Relevant articles and documents

Synthesis of Z-alkenes from Rh(I)-catalyzed olefin isomerization of β,γ-unsaturated ketones

Developing olefin isomerization reactions to reach kinetically controlled Z-alkenes is challenging because formation of trans-alkenes is thermodynamically favored under the traditional catalytic conditions using acids, bases, or transition metals as the catalysts. A new synthesis of Z-alkenes from Rh(I)-catalyzed olefin isomerization of β,γ-unsaturated ketones to α,β-unsaturated ketones was developed, providing an easy and efficient way to access various Z-enones.