1455451-90-7

Basic information

• Product Name: (3R,4R,5S)-diethyl 5-[2-(2-benzyloxyethyl)phenyl]-4-formyl-3-methylpyrrolidine-2,2-dicarboxylate
• Synonyms: (3R,4R,5S)-diethyl 5-[2-(2-benzyloxyethyl)phenyl]-4-formyl-3-methylpyrrolidine-2,2-dicarboxylate
• CAS NO: 1455451-90-7
• Molecular Weight: 467.562
• Mol File: 1455451-90-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3R,4R,5S)-diethyl 5-[2-(2-benzyloxyethyl)phenyl]-4-formyl-3-methylpyrrolidine-2,2-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4R,5S)-diethyl 5-[2-(2-benzyloxyethyl)phenyl]-4-formyl-3-methylpyrrolidine-2,2-dicarboxylate(1455451-90-7)
• EPA Substance Registry System: (3R,4R,5S)-diethyl 5-[2-(2-benzyloxyethyl)phenyl]-4-formyl-3-methylpyrrolidine-2,2-dicarboxylate(1455451-90-7)

Safety Data

• Hazardous Substances Data: 1455451-90-7(Hazardous Substances Data)

Upstream product

• 123-73-9 trans-Crotonaldehyde 
• 1455451-87-2 (E)-diethyl N-[2-(2-benzyloxyethyl)benzylideneamino]malonate 
• 100-39-0 benzyl bromide 
• 1074-16-4 2-bromophenylethyl alcohol 
• 119367-94-1 2-<2-(Benzyloxy)ethyl>benzaldehyde 

Downstream Products

• 1455451-93-0 (3R,4R,5S)-diethyl 5-[2-(2-benzyloxyethyl)phenyl]-4-hydroxymethyl-3-methylpyrrolidine-2,2-dicarboxylate 
• 1455451-99-6 (3R,4R,5S)-diethyl 4-(tert-butyldimethylsilyloxymethyl)-5-[2-(2-hydroxyethyl)phenyl]-3-methylpyrrolidine-2,2-dicarboxylate 
• 1455451-96-3 (3R,4R,5S)-diethyl 5-[2-(2-benzyloxyethyl)phenyl]-4-(tert-butyldimethylsilyloxymethyl)-3-methylpyrrolidine-2,2-dicarboxylate 

Relevant articles and documents

The organocatalytic enantioselective [3+2] cycloaddition reaction of α,β-unsaturated aldehydes with azomethine ylides applied to the asymmetric synthesis of densely substituted pyrroloisoquinolines

The synthesis of densely functionalized pyrrolo[2,1-a]isoquinolines was accomplished using the organocatalytic [3+2] cycloaddition between enals and azomethine ylides under iminium catalysis developed in our group some years ago as the key step. The cyclo