145653-04-9

Downstream Products

• 145681-42-1 (E)-(R)-4-(Diphenyl-phosphinoyl)-5-methyl-hex-2-en-1-ol 
• 145681-30-7 {(2S,3R)-3-[(R)-1-(Diphenyl-phosphinoyl)-2-methyl-propyl]-oxiranyl}-methanol 
• 148406-90-0 {(2R,3S)-3-[(R)-1-(Diphenyl-phosphinoyl)-2-methyl-propyl]-oxiranyl}-methanol 
• 145653-23-2 {(2S,3R)-3-[(S)-1-(Diphenyl-phosphinoyl)-2-methyl-propyl]-oxiranyl}-methanol 
• 171356-57-3 (2S,3R,4S)-2-Benzylamino-4-(diphenyl-phosphinoyl)-3-hydroxy-5-methyl-hexanoic acid 
• 148314-40-3 (2S,3S)-3-[(R)-1-(Diphenyl-phosphinoyl)-2-methyl-propyl]-oxirane-2-carboxylic acid 
• 148314-49-2 4-diphenylphosphinoyl-5-methylhex-2-enyl tert butyl(dimethyl)silyl ether 

Relevant academic research and scientific papers

The Synthesis of δ-Hydroxy Allylic Phosphine Oxides by Palladium(II)-catalysed Allylic Acetate Transposition

Palladium(II)-catalysed allylic acetate transposition, when driven by the diphenylphosphinoyl (Ph2PO) group, is regiospecific (acetate moves away from the Ph2PO group), stereoselective (the new double bond is E), and stereospecific (the acetate moves supr