148314-49-2

Basic information

• Product Name: 4-diphenylphosphinoyl-5-methylhex-2-enyl tert butyl(dimethyl)silyl ether
• CAS NO: 148314-49-2
• Molecular Weight: 428.627
• Mol File: 148314-49-2.mol

Chemical Properties

• CAS DataBase Reference: 4-diphenylphosphinoyl-5-methylhex-2-enyl tert butyl(dimethyl)silyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: 4-diphenylphosphinoyl-5-methylhex-2-enyl tert butyl(dimethyl)silyl ether(148314-49-2)
• EPA Substance Registry System: 4-diphenylphosphinoyl-5-methylhex-2-enyl tert butyl(dimethyl)silyl ether(148314-49-2)

Safety Data

• Hazardous Substances Data: 148314-49-2(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 145653-04-9 (E)-4-diphenylphosphinoyl-5-methylhex-2-en-1-ol 

Relevant articles and documents

Stereocontrolled Synthesis of R or S, E or Z Unsaturated α-Amino Acids by Enantio- and Diastereoselective Epoxidation of δ-Hydroxy Allylic Phosphine Oxides

Epoxidation of δ-hydroxy allylic phosphine oxides 5 with m-CPBA can be syn selective.All stereoisomers of epoxy alcohols 6 are available when this method is used in tandem with an anti selective Sharpless kinetic resolution.The stereoisomers of epoxy alco

Diastereoselective Epoxidation of Allylic Phosphine Oxides

Allylic phosphine oxides are epoxidised anti selectively by m-CPBA, but this selectivity can be reversed if the allylic phosphine oxide is also an allylic alcohol.