1456808-65-3Relevant academic research and scientific papers
Aryl gem-Difluorovinyl Pinacolboronates: Synthesis and Utility for Suzuki-Miyaura Coupling Reaction
Zhou, Jun,Jiang, Bingyao,Guo, Ming,Sumii, Yuji,Shibata, Norio
, p. 1439 - 1442 (2020)
The synthesis of unstable aryl difluorovinyl pinacolboronates was achieved by the dehydrofluorination of α-trifluoromethyl arylmethyl pinacolboronates with LDA. These aryl difluorovinyl pinacolboronates can be used for Suzuki-Miyaura coupling with various
Facile synthesis of unsymmetrical 1,1-diaryl-2,2-difluoroethenes via stepwise coupling of 1,1-dibromo-2,2-difluoroethenes
Fujita, Takeshi,Suzuki, Naoto,Ichitsuka, Tomohiro,Ichikawa, Junji
, p. 97 - 101 (2013/10/01)
Unsymmetrical 1,1-diaryl-2,2-difluoroethenes were synthesized from 1,1-dibromo-2,2-difluoroethene, which is commercially available, via the Suzuki-Miyaura coupling in a stepwise fashion. Suitable ligands for each coupling process were used to achieve selective synthesis of these diaryldifluoroethenes.
