1456901-39-5Relevant academic research and scientific papers
Synthesis of amphiphilic diblock copolymer using heterobifunctional linkers, connected by a photodegradable N-(2-Nitrobenzyl)imide structure and available for two different click chemistries
Yamamoto, Shota,Tochigi, Hidemi,Yamazaki, Shuya,Nakahama, Seiichi,Yamaguchi, Kazuo
, p. 481 - 489 (2016)
Two photodegradable heterobifunctional linkers (PHBL) connected by a N-(2-nitrobenzyl)imide structure have been developed as tools to obtain photodegradable diblock copolymers with precisely controlled molecular weight. They can undergo two different clic
A heterobifunctional linker bearing azide-reactive alkyne and thiol-reactive maleimide connected with N-(2-Nitrobenzyl)imide to synthesize photocleavable diblock copolymers
Yamamoto, Shota,Nakahama, Seiichi,Yamaguchi, Kazuo
, p. 791 - 793 (2013/09/02)
A novel heterobifunctional linker 1 connected with photocleavable N-(2-nitrobenzyl)imide has been developed. Hydrophobic polystyrene (PS), hydrophilic poly(ethylene oxide) (PEO), and thermosensitive poly(N- isopropylacrylamide) (PNIPAM) containing thiol or azide at the terminal, synthesized by a living radical polymerization or a transformation of terminal functional groups, were coupled with the alkyne and maleimide protected as the furan adduct at both terminals of 1 to synthesize three types of photocleavable diblock copolymers in high yields.
