145782-40-7Relevant academic research and scientific papers
Radical cyclization of 1-allyloxy-2-halo-1-silacyclopentane. Application to stereoselective synthesis of 1,4,6-triols
Matsumoto,Miura,Oshima,Utimoto
, p. 7031 - 7034 (1992)
Treatment of 1-allyloxy-1-phenyl-2-bromo-1-silacyclopentane with n-Bu3SnH in the presence of catalytic amount of Et3B provided 1-sila-2-oxabicyclo[3.3.0]-octane which was converted into 1,4,6-triol.
Triethylborane-induced radical cyclization of 1-allyloxy-2-halosilacyclopentane. Stereoselective synthesis of 1,3,6-triols starting from silacyclobutane
Matsumoto,Miura,Oshima,Utimoto
, p. 625 - 634 (2007/10/02)
1-Allyloxy-2-bromo-1-phenylsilacyclopentane was synthesized by a ring-enlargement reaction of 1-allyloxy-1-phenylsilacyclobutane with LiCHBr2. The treatment of 1-allyloxy-2-bromo-1-phenylsilacyclopentane with n-Bu3SnH in the presence
