Radical cyclization of 1-allyloxy-2-halo-1-silacyclopentane. Application to stereoselective synthesis of 1,4,6-triols

DOI: 10.1016/S0040-4039(00)60925-5

Source and publish data:

Tetrahedron Letters p. 7031 - 7034 (1992)

Update date:2022-08-16

Topics:

Authors:

Matsumoto

Miura Miura

Oshima Oshima

Utimoto Utimoto

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Article abstract of DOI:10.1016/S0040-4039(00)60925-5

Treatment of 1-allyloxy-1-phenyl-2-bromo-1-silacyclopentane with n-Bu₃SnH in the presence of catalytic amount of Et₃B provided 1-sila-2-oxabicyclo[3.3.0]-octane which was converted into 1,4,6-triol.

Full text of DOI:10.1016/S0040-4039(00)60925-5

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