1458033-20-9

Basic information

• Product Name: (2R,3R,4R)-6-(benzyloxy)-3-(methoxymethoxy)-4-methylhexane-1,2-diol
• Synonyms: (2R,3R,4R)-6-(benzyloxy)-3-(methoxymethoxy)-4-methylhexane-1,2-diol
• CAS NO: 1458033-20-9
• Molecular Weight: 298.379
• Mol File: 1458033-20-9.mol

Chemical Properties

• CAS DataBase Reference: (2R,3R,4R)-6-(benzyloxy)-3-(methoxymethoxy)-4-methylhexane-1,2-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R,4R)-6-(benzyloxy)-3-(methoxymethoxy)-4-methylhexane-1,2-diol(1458033-20-9)
• EPA Substance Registry System: (2R,3R,4R)-6-(benzyloxy)-3-(methoxymethoxy)-4-methylhexane-1,2-diol(1458033-20-9)

Safety Data

• Hazardous Substances Data: 1458033-20-9(Hazardous Substances Data)

Upstream product

• 389086-15-1 (4R)-4-benzyl-3-(4-benzyloxy-1-oxobutyl)-2-oxazolidinone 
• 1458033-17-4 (R)-4-benzyl-3-((R)-4-(benzyloxy)-2-methylbutanoyl) oxazolidin-2-one 
• 96154-47-1 (R)-2-methyl-1,4-butanediol 4-benzyl ether 
• 1458033-18-5 (4S,5R)-7-(benzyloxy)-5-methylhept-1-en-4-ol 
• 1458033-19-6 C₁₇H₂₆O₃ 
• 4541-14-4 4-benzyloxy-butan-1-ol 
• 100-39-0 benzyl bromide 
• 10385-30-5 4-(benzyloxy)butanoic acid 
• 91550-14-0 (2R)-4-(Benzyloxy)-2-methyl-1-butanal 

Downstream Products

• 1458033-21-0 (R)-2-((1R,2R)-4-(benzyloxy)-1-(methoxymethoxy)-2-methylbutyl)oxirane 
• 1458033-22-1 (5R,6R)-5-((R)-4-(benzyloxy)butan-2-yl)-13,13,14,14-tetramethyl-2,4,12-trioxa-13-silapentadec-8-yn-6-ol 
• 1458033-23-2 (5R,6R,Z)-5-((R)-4-(benzyloxy)butan-2-yl)-13,13,14,14-tetramethyl-2,4,12-trioxa-13-silapentadec-8-en-6-ol 

Relevant articles and documents

Total synthesis of attenols A and B

A concise approach for the total synthesis of attenols A and B is described involving MacMillan's α-aminooxylation, Evan's asymmetric alkylation, Brown's allylation, and spiro-ketalization as key steps. This approach has successfully demonstrated the α-aminooxylation protocol for the construction of the anti-1,3-diol unit.