145835-83-2

Upstream product

• 145835-80-9 benzyl O-<2-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)-ethylidene>-3-O-methyl-β-D-glucopyranosyl>-(1<*>3)-2-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-α-D-glucopyranoside 
• 145835-76-3 benzyl 4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-2,3-O-(1,1,3,3-tetraisopropyl-1,3-disiloxane-1,3-diyl)-α-D-glucopyranoside 
• 145835-75-2 benzyl 4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-α-D-glucopyranoside 
• 98-88-4 benzoyl chloride 
• 19488-49-4 methyl 2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 146530-60-1 C₃₅H₄₀O₁₇ 
• 138857-67-7 benzyl 2,3-di-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-α-D-glucopyranoside 

Relevant academic research and scientific papers

A novel convergent strategy for the construction of oligosaccharides using TIPS-protected glycosides. Synthesis of fragments related to glycolipids of Mycobacterium smegmatis

4,6-O-Pyruvylated glucosides 1 were converted to the corresponding glucosyl fluorides 3 and 2,3-O-TIPS-protected glucopyranosides 5, respectively. Lewis-acid-catalyzed coupling of 3 and 5 afforded the pyruvylated disaccharides 6 one of which was further converted via the dissacharide donor 8 to di- and trisaccharide fragments of Mycobacterium smegmatis.