145938-92-7Relevant academic research and scientific papers
TRICHLOROMETHYLATION OF FLUOROKETONES
Zeifman, Yu. V.
, p. 370 - 373 (1992)
The nuclophilic trichloromethylation of fluoroketones was carried out by the reductive addition of CCl4 in the presence of aluminum or by the reaction of trichloroacetic acid in HMPTA.The trichloromethylcarbinols obtained were used in the synthesis of perfluorinated tertiary alcohols and trifluoromethylated 1,1-dichlorooxiranes. Keywords: fluoroketones, trichloromethylation, fluorine-containing trichloromethylcarbinols and 1,1-dichlorooxiranes, synthesis.
Synthetic application of 3,3-dichloro-1, 1, 1-trifluoroacetone (DCTFA) and 3,3,3-trichloro-1, 1, 1-trifluoroacetone (TCTFA) for trifluorolactic acid derivatives
Ishii, Akihiro,Kanai, Masatomi,Yasumoto, Manabu,Inomiya, Kenjin,Kuriyama, Yokusu,Katsuhara, Yutaka
, p. 567 - 571 (2004)
Synthetic application of 3,3-dichloro-1,1,1-trifluoroacetone (DCTFA) and 3,3,3-trichloro-1,1,1-trifluoroacetone (TCTFA) for industrially important trifluorolactic acid derivatives is described. Trifluorolactic acid was obtained by hydrolysis of DCTFA unde
