Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 370 - 373 (1992)
Update date:2022-08-03
Topics:
Zeifman, Yu. V.
The nuclophilic trichloromethylation of fluoroketones was carried out by the reductive addition of CCl4 in the presence of aluminum or by the reaction of trichloroacetic acid in HMPTA.The trichloromethylcarbinols obtained were used in the synthesis of perfluorinated tertiary alcohols and trifluoromethylated 1,1-dichlorooxiranes. Keywords: fluoroketones, trichloromethylation, fluorine-containing trichloromethylcarbinols and 1,1-dichlorooxiranes, synthesis.
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