145950-10-3Relevant academic research and scientific papers
The co-oxidation of conjugated enynes. A convenient synthesis of β-sulfoxy acetylenic carbinols
Wang, Xiaoheng,Ni, Zhijie,Lu, Xiujing,Smith, Temeika Y.,Rodriguez, Augusto,Padwa, Albert
, p. 5917 - 5920 (1992)
Several β-sulfoxy substituted acetylenic carbinols were prepared by the addition of thiyl radicals and oxygen to conjugated enynes.
-Sigmatropic Rearrangement of β-Phenylsulfonyl Propargylic Sulfenates as a Method for Preparing 1,4-Bis(phenylsulfonyl)-1,3-butadienes
Wang, Xiaoheng,Ni, Zhijie,Lu, Xiujing,Hollis, Andrea,Banks, Harold,et al.
, p. 5377 - 5385 (2007/10/02)
Several β-sulfoxy-substituted acetylenic carbinols were prepared by the addition of thiyl radicals and oxygen to conjugated enynes.The products obtained are derived from thiyl radical attack at the olefinic bond to generate a propargylic radical.Capture o
Application of the 2,3-sigmatropic rearrangement of β-sulfonyl acetylenic carbinols toward the synthesis of 1,4-bis(phenylsulfonyl)-1,3-butadienes
Ni,Wang,Rodriguez,Padwa
, p. 7303 - 7306 (2007/10/02)
Sulfenic esters of β-sulfur substituted acetylenic carbinols undergo 2,3-sigmatropic rearrangement to produce allenylic sulfoxides which were converted to 1,4-bis(phenylsulfonyl)-1,3-dienes of α,β-unsaturated ketones.
