150587-52-3Relevant academic research and scientific papers
-Sigmatropic Rearrangement of β-Phenylsulfonyl Propargylic Sulfenates as a Method for Preparing 1,4-Bis(phenylsulfonyl)-1,3-butadienes
Wang, Xiaoheng,Ni, Zhijie,Lu, Xiujing,Hollis, Andrea,Banks, Harold,et al.
, p. 5377 - 5385 (2007/10/02)
Several β-sulfoxy-substituted acetylenic carbinols were prepared by the addition of thiyl radicals and oxygen to conjugated enynes.The products obtained are derived from thiyl radical attack at the olefinic bond to generate a propargylic radical.Capture o
