1459721-83-5

Basic information

• Product Name: 1,3,7-triphenyl-1,4-dihydro[1,3]oxazolo[4,5-g][1,2,4]benzotriazin-4-yl
• Synonyms: 1,3,7-triphenyl-1,4-dihydro[1,3]oxazolo[4,5-g][1,2,4]benzotriazin-4-yl
• CAS NO: 1459721-83-5
• Molecular Weight: 401.447
• Mol File: 1459721-83-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3,7-triphenyl-1,4-dihydro[1,3]oxazolo[4,5-g][1,2,4]benzotriazin-4-yl(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,7-triphenyl-1,4-dihydro[1,3]oxazolo[4,5-g][1,2,4]benzotriazin-4-yl(1459721-83-5)
• EPA Substance Registry System: 1,3,7-triphenyl-1,4-dihydro[1,3]oxazolo[4,5-g][1,2,4]benzotriazin-4-yl(1459721-83-5)

Safety Data

• Hazardous Substances Data: 1459721-83-5(Hazardous Substances Data)

Upstream product

• 1986-61-4 N²-(4-Nitrophenyl)benzimidamide 
• 24967-77-9 N′-(4-iodophenyl)benzamidine 
• 21719-91-5 N′-(4-bromophenyl)benzamidine 
• 7035-69-0 N′-(4-chlorophenyl)benzamidine 
• 1236358-07-8 N′-(4-fluorophenyl)benzamidine 
• 1236358-03-4 N-(4-methoxyphenyl)benzimidamide 
• 1859-00-3 N'-(4-methyphenyl)benzamidine 
• 1403990-53-3 N-(7-oxo-1,3-diphenyl-1,7-dihydrobenzo[e][1,2,4]triazin-6-yl)benzamide 
• 1527-91-9 N-phenylbenzamidine 
• 1459721-94-8 N′-n-hexyl-N-(1,7-dihydro-7-oxo-1,3-diphenylbenzo[e]-[1,2,4]triazin-6-yl)benzimidamide 
• 1459721-89-1 N′-(4-bromophenyl)-N-(1,7-dihydro-7-oxo-1,3-diphenylbenzo[e][1,2,4]triazin-6-yl)benzamidine 
• 22751-79-7 1,3-diphenylbenzo[e]-[1,2,4]triazin-7(1H)-one 
• 1459721-87-9 N′-(4-fluorophenyl)-N-(1,7-dihydro-7-oxo-1,3-diphenylbenzo[e][1,2,4]triazin-6-yl)benzimidamide 
• 1459721-86-8 N-(1,7-dihydro-7-oxo-1,3-diphenylbenzo[e][1,2,4]triazin-6-yl)-N′-(4-methoxyphenyl)benzimidamide 

Downstream Products

• 1459721-97-1 1,3,7,8-tetraphenyl-4,8-dihydro-1H-imidazo[4,5-g][1,2,4]benzotriazin-4-yl 
• 1459722-05-4 8-n-hexyl-1,3,7-triphenyl-4,8-dihydro-1H-imidazo[4,5-g][1,2,4]benzotriazin-4-yl 
• 1403990-53-3 N-(7-oxo-1,3-diphenyl-1,7-dihydrobenzo[e][1,2,4]triazin-6-yl)benzamide 
• 1316792-97-8 6-amino-1,3-diphenylbenzo[e][1,2,4]triazin-7-(1H)-one 
• 1459721-96-0 6-(n-hexylamino)-1,3-diphenylbenzo[e][1,2,4]triazin-7(1H)-one 
• 1459721-84-6 N-(1,7-dihydro-7-oxo-1,3-diphenylbenzo[e][1,2,4]triazin-6-yl)-N′-phenylbenzimidamide 
• 1459721-94-8 N′-n-hexyl-N-(1,7-dihydro-7-oxo-1,3-diphenylbenzo[e]-[1,2,4]triazin-6-yl)benzimidamide 
• 1569089-32-2 2,6,7-triphenyl-7H-imidazo[4,5-f]benzoxazole 

Relevant articles and documents

Synthesis and properties of imidazolo-fused benzotriazinyl radicals

1,3-Diphenylbenzo[e][1,2,4]triazin-7(1H)-one, the oxidation product of 1,3-diphenyl-1,4-dihydro-1,2,4-benzotriazin-4-yl (Blatter's radical), reacts with N′-arylbenzamidines in PhMe at ca. 100 °C in the presence of N,N-diisopropylethylamine (Hu?nig's base) (1 equiv.) to give N′-aryl-N-(1,7-dihydro-7-oxo-1,3-diphenylbenzo[e][1,2,4]triazin-6-yl) benzimidamides in 49-95% yield. In neat AcOH heated at ca. 120 °C, N′-aryl-N-(1,7-dihydro-7-oxo-1,3-diphenylbenzo[e][1,2,4]triazin-6-yl) benzimidamides cyclodehydrate to give the novel 8-substituted 1,3,7-triphenyl-4,8-dihydro-1H-imidazo[4,5-g][1,2,4]benzotriazin-4-yls in 13-81% yield. During the optimization of this cyclodehydration an additional oxazole fused benzotriazinyl radical 1,3,7-triphenyl-1,4-dihydro[1,3]oxazolo[4,5-g][1,2, 4]benzotriazin-4-yl was isolated as a side product and characterized. The CV and EPR data of the imidazolo- and oxazolo-fused radicals are presented as well as single crystal X-ray structures of 1,3,7-triphenyl-1,4-dihydro-[1,3]oxazolo[4,5- g][1,2,4]benzotriazin-4-yl and 1,3,7,8-tetraphenyl-4,8-dihydro-1H-imidazo[4,5-g] [1,2,4]benzotriazin-4-yl.