146237-55-0Relevant academic research and scientific papers
Reaction of HCl with photoproduced base-substituted manganese carbonyl radicals
Byers, Blaine H.,Curran, Timothy P.,Thompson, Michael J.,Sauer, Linda J.
, p. 459 - 460 (2008/10/08)
Near-UV irradiation of Mn2(CO)8L2 (L = PBu3, P(OEt)3) in the presence of HCl and a variety of solvents yields both HMn(CO)4L and Mn(CO)4(L)Cl. Evidence suggests the mechanism involves oxidative addition of HCl to 15- and 17-electron metal carbonyl radicals.
