97981-80-1Relevant academic research and scientific papers
Photochemical reactions between dinuclear metal carbonyl complexes and alkyl halides. Formal oxidative addition across a metal-metal single bond proceeding by a free radical chain mechanism
Biddulph, Michael A.,Davis, Reg,Wilson, Fiona I. C.
, p. 277 - 293 (2007/10/02)
Photochemical reactions between (L = CO, PBu3, PEt3, P(OMe)3, P(OPh)3, PPh3) and alkyl halides (RX) yield both alkyl and halo complexes, and , in equimolar quantities.Kinetic and quantum yield studies suggest that these reactions proceed by a radical chain pathway involving CO dissociation from the dinuclear complex and metal-metal bond homolysis of the coordinatively unsaturated dinuclear intermediate.
Thermal reactions between and alkyl halides; evidence for an outer-sphere electron transfer process
Davis, Reg,Wilson, Fiona I.C.
, p. 55 - 63 (2007/10/02)
Thermal reactions between 2(CO)8(PBu3)2> and some alkyl halides (RX) yield both 4PBu3> and 4PBu3>.Kinetic and other studies suggest that the reactio
