14629-63-1Relevant academic research and scientific papers
Synthesis and characterization of new (chloro)aminosilanes: X-ray crystal structure of [(2,6-Me2C6H3NH)2SiCl2]
Walawalkar, Mrinalini G.,Murugavel, Ramaswamy
, p. 229 - 238 (2001)
Starting from racemic α-methylbenzyl amine or α-methylbenzyl bromide, new (amino)trichlorosilanes (MePhC(H))(SiMe3)NSiCl3(1) and (MePhC(H))(2,6-Me2C6H3) NSiCl3 (2) have been synthesized in
Synthesis of Urea Derivatives from CO2 and Silylamines
Xu, Maotong,Jupp, Andrew R.,Ong, Maegan S. E.,Burton, Katherine I.,Chitnis, Saurabh S.,Stephan, Douglas W.
supporting information, p. 5707 - 5711 (2019/04/16)
A series of thirty-three N,N′-diaryl, dialkyl, and alkyl-aryl ureas have been prepared in pyridine or toluene by reaction of silylamines with CO2. This protocol is shown to provide facile access to 13C-labeled ureas, as well as chiral and macrocyclic ureas. These reactions proceed through initial generation of the corresponding silylcarbamates, which subsequently react with silylamine under thermal conditions to afford the thermodynamically favored urea and disilyl ether.
Metal-assisted fragmentation of N-aryl- and -alkyl-N-trimethylsilylaminosulfur chlorides and N-aryl- and -alkyl-aminosulfur chlorides in the presence of conjugated dienes: Synthesis and reactivity of 2-substituted-3,6-dihydro-1,2-thiazines
Bryce, Martin R.,Chesney, Antony,McKelvey, Graham N.,Batsanov, Andrei S.,Howard, Judith A. K.,Anderson, Martin
, p. 1825 - 1831 (2007/10/03)
N-Alkyl- and -aryl-N-trimethylsilylaminosulfur chlorides 2 and N-aryl- and -alkyl-aminosulfur chlorides 8 fragment in the presence of silver ions and a conjugated diene to yield 2-substituted-3,6-dihydro-1,2-thiarines 6 as the major products, possibly via
