146335-32-2Relevant academic research and scientific papers
A new convergent approach to biphenomycin antibiotics
Paintner, Franz F.,G?rler, Klaus,Voelter, Wolfgang
, p. 522 - 526 (2007/10/03)
A new, convergent approach to the biaryl key intermediate of Schmidt's biphenomycin B total synthesis has been accomplished via a palladacycle complex catalyzed Stille cross-coupling of two o-tyrosine building blocks.
Total synthesis of the biphenomycins; V. Synthesis of biphenomycin A
Schmidt,Leitenberger,Griesser,Schmidt,Meyer
, p. 1248 - 1254 (2007/10/02)
The total synthesis of biphenomycin A is described. Two of the five stereogenic centres were formed by enantioselective hydrogenation of the corresponding didehydroamino acids using the rhodium-DIPAMP catalyst and the two stereogenic centres of the α-amin
