14641-64-6

Basic information

• Product Name: meso-Tetraphenylporphyrin-Ag(II)
• Synonyms: 5,10,15,20-Tetraphenyl-21H,23H-porphine silver(II)
• CAS NO: 14641-64-6
• Molecular Formula: C₄₄H₂₈AgN₄
• Molecular Weight: 720.603
• Mol File: 14641-64-6.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: meso-Tetraphenylporphyrin-Ag(II)(CAS DataBase Reference)
• NIST Chemistry Reference: meso-Tetraphenylporphyrin-Ag(II)(14641-64-6)
• EPA Substance Registry System: meso-Tetraphenylporphyrin-Ag(II)(14641-64-6)

Safety Data

• Hazardous Substances Data: 14641-64-6(Hazardous Substances Data)

Usage

General Description

Meso-tetraphenylporphyrin-Ag(II) is a chemical compound that consists of a porphyrin ring with four phenyl groups attached to it, as well as an Ag(II) ion. It is an organometallic complex with the silver ion coordinated to the porphyrin ring. meso-Tetraphenylporphyrin-Ag(II) has potential applications in catalysis and material science due to the unique properties of the porphyrin ring and the reactivity of the silver ion. Its structure and reactivity make it a promising candidate for use in the development of new materials for various technological applications. Additionally, its interaction with light and its ability to undergo redox reactions make it a subject of interest in the field of photochemistry.

Upstream product

• 917-23-7 5,10,15,20-tetraphenyl-21H,23H-porphine 
• 563-63-3 silver(I) acetate 
• 917-23-7 5,15,10,20-tetraphenylporphyrin 
• 14074-80-7 zinc tetraphenylporphyrin 

Downstream Products

• 917-23-7 5,10,15,20-tetraphenyl-21H,23H-porphine 
• 7440-22-4 silver 
• 20667-12-3 silver(l) oxide 
• 131214-92-1 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato silver(II) 

Relevant articles and documents

Structure and stability of H+ associates of (5,10,15,20- tetraphenylporphinato)silver(II) in trifluoroacetic acid

Direct experimental confirmation of the formation of ion-molecular associates of (5,10,15,20-tetraphenyl-21H,23H-porphinato)silver(II) (AgTPP) with solvent protons in CF3COOH is obtained by means of 1H NMR spectroscopy. Their structure and spectral properties, as well as the kinetics of dissociation on metal-nitrogen bonds, depending on the concentration of CF3COOH (89-100%) and temperature (298-328 K), are studied It is shown that AgTPP acts as a C-base during the formation of H+ associates, the coordination centers of which have a high stability.

Synthesis of Ag(II) 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-Tetraphenylporphyrin and its facile demetalation to 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-Tetraphenylporphyrin

A novel one-step strategy for the synthesis of 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-Tetraphenylporphyrin using AgIIOBP is described. AgIIOBP was synthesized and was. Bromination of AgIITPP was carried out in a one-step reaction by varying the subseque