1464148-75-1Relevant academic research and scientific papers
Five additional macrocycles that allow Na+ ion-templated threading of guest units featuring a single urea or amide functionality
Lin, You-Han,Lai, Chien-Chen,Chiu, Sheng-Hsien
, p. 2907 - 2917 (2014/05/06)
Five analogues of the macrocycle BPX26C6 are also capable of recognizing single urea and/or amide functionalities in the presence of templating Na + ions. We have unambiguously confirmed the formation of such [2]pseudorotaxane complexes in solution through syntheses of the corresponding [2]rotaxanes. This journal is the Partner Organisations 2014.
Sodium ions template the formation of rotaxanes from BPX26C6 and nonconjugated amide and urea functionalities
Lin, You-Han,Lai, Chien-Chen,Liu, Yi-Hung,Peng, Shie-Ming,Chiu, Sheng-Hsien
, p. 10231 - 10236 (2013/10/21)
Picking up the thread: The macrocycle bis-p-xylyl[26]crown-6 is capable of forming pseudorotaxane-like structures with single, nonconjugated urea or amide moieties when assisted by templating Na+ ions (see example). By using this approach, rotaxanes were synthesized with glycine residues or the repeating unit of nylon-6,6 as key components in the threadlike units. Copyright
