146463-39-0

Usage

Physical properties

white crystalline solid

Common use

reactant in organic synthesis

Applications

production of polymers, resins, plastics, dyes, pharmaceuticals, specialty chemicals

Chemical reactivity

undergoes Diels-Alder reactions and other transformations

Safety

should be handled with care and in accordance with safety regulations due to potential health and environmental hazards.

Upstream product

• 79-37-8 oxalyl dichloride 
• 72223-17-7 1-trimethylsilyloxy-1,2-diphenylethylene 

Downstream Products

• 146463-40-3 N-p-tolyl-2,4-dioxo-3,4-diphenylbutanamide 
• 146463-41-4 N-(4-Methoxy-phenyl)-2,4-dioxo-3,4-diphenyl-butyramide 
• 330838-10-3 2-benzyl-2,5,6-triphenyl-[1,3]dioxin-4-one 
• 123858-72-0 2-p-dimethylaminophenyl-5,6-diphenyl-4H-1,3-oxazin-4-one 
• 1341189-45-4 3,4,6,8,9-pentaphenyl-5,7-dioxa-1-azabicyclo[4.4.1]undeca-3,8-diene-2,10-dione 
• 70375-96-1 N-(4-methoxy-phenyl)-3-oxo-2,3-diphenyl-propionamide 
• 70375-95-0 2-Benzoyl-N-(4-methylphenyl)-2-phenylacetamid 
• 69974-15-8 3-benzoyl-3,5,6-triphenyl-2H-pyran-2,4(3H)-dione 
• 146463-48-1 4,6-Dihydroxy-5,6-diphenyl-1,6-dihydro-2H-pyridazin-3-one 

Relevant academic research and scientific papers

Experimental support for planar pseudopericyclic transition states in thermal cheletropic decarbonylations

(Chemical Equation Presented) Low-temperature crystal structures of three pyrrolediones (3-5) and a furandione (9) were obtained and compared to structurally related compounds that cannot undergo decarbonylation. Systematic trends in bond lengths and angl

Five-Membered 2,3-Dioxo Heterocycles: XLV. Thermolysis of 5-Aryl-4-phenyl-2,3-dihydrofuran-2,3-diones in the Absence of Other Partners and in the Presence of Carbonyl Compounds

Aroyl(phenyl)ketenes generated by thermolysis of 5-aryl-4-phenyl-2,3- dihydrofuran-2,3-diones undergo [4+2]-cyclodimerization to 3-aroyl-6-aryl-3,5- diphenyl-3,4-dihydro-2H-pyran-2,4-diones. Heating of the latter leads to rearrangement with formation of 4-aroyloxy-6-aryl-3,5-diphenyl-2H-pyran-2-ones. Thermolysis of 5-aryl-4-phenyl-2,3-dihydrofuran-2,3-diones in the presence of carbonyl compounds yields 6-aryl-5-phenyl-4H-1,3-dioxin-4-ones.

FIVE-MEMBERED 2,3-DIOXOHETEROCYCLES XXVII. 4,5-DIPHENYL-2,3-DIHYDRO-2,3-FURANDIONE. SYNTHESIS AND REACTIONS WITH AMINO COMPOUNDS

4,5-Diphenyl-2,3-dihydro-2,3-furandione reacts with amines and hydrazines to form the amides and hydrazides of 2,3-dioxo-3,4-diphenylbutyric acid.The products exist preferentially in the form of the respective five-and six-membered ring isomers and readil