146499-37-8

Upstream product

• 98819-68-2 3-phenyl-(2R,3R)-oxiran-2-ylmethanol 
• 121745-57-1 (2R,3R)-3-azido-3-phenyl-propane-1,2diol 
• 153829-27-7 (1R,2R)-3-amino-3-phenyl-1,2-propanediol 
• 104196-23-8 (2S,3S)-2,3-epoxy-3-phenyl-1-propanol 
• 108-24-7 acetic anhydride 
• 153704-80-4 (2R,3R)-1,2-dihydroxy-3-(2,2,2-trichloroethoxycarbonylamino)-3-phenylpropane 

Relevant academic research and scientific papers

Total Synthesis of Mugineic Acid. Efficient Use of the Phenyl Group as the Carboxyl Synthon

Stereoselective total synthesis of mugineic acid (1), a unique phytosiderophore from roots of barley, has been achieved from readily available (2S,3S)- and (2R,3R)-2,3-epoxycinnamyl alcohols (5) and (6).The key step is the oxidation of the phenyl group to the carboxylic acid by use of the ruthenium trichloride-sodium metaperiodate system.

Efficient Synthesis of Mugineic Acid, A Typical Phytosiderophore, Utilizing the Phenyl Group as the Carboxyl Synthon

Stereoselective total synthesis of mugineic acid, a unique phytosiderophore from roots of barley, has been achieved from (2R,3R)- and (2S,3S)-2,3-epoxycinnamyl alcohols employing the phenyl group as the carboxyl synthon.