146652-97-3

Upstream product

• 455-18-5 4-CF₃C₆H₄CN 
• 352-11-4 1-chloromethyl-4-fluorobenzene 

Downstream Products

• 35923-46-7 1-(4-fluoro-phenyl)-2-(4-trifluoromethyl-phenyl)-ethane-1,2-dione 
• 1594937-22-0 5-(4-fluorophenyl)-2-phenyl-4-[4-(trifluoromethyl)phenyl]imidazole 
• 1594937-33-3 4-(tert-butyldimethylsilylperoxy)-4-(4-fluorophenyl)-2-phenyl-5-[4-(trifluoromethyl)phenyl]-4H-isoimidazole 

Relevant academic research and scientific papers

The chemiexcitation of the chemiluminescence of lophine peroxide anions via a partially cyclic transition state

It was shown that acyclic intermediates play a role in the chemiexcitation of the chemiluminescence (CL) of lophine peroxides in addition to the dioxetane intermediates. Because the CL efficiencies of position-isomers (R)-9 and (R)-10, which theoretically give the common dioxetane intermediate, were different, the different CL efficiencies are attributable to the CL mechanism involving a partially cyclic transition structure at the chemiexcitation step. The study of isomeric 2-phenyl-4-p-X-phenyl-5-p-Y-phenyl-4-silylated peroxy-isoimidazals [(R)-9: X = CF3, Y = F and (R)-10: X = F, Y = CF3] confirmed the existence of lophine peroxide anion intermediates in the chemiluminescence of lophine peroxides in addition to the dioxetane intermediates. Copyright