146896-99-3

Upstream product

• 109-47-7 dibutyl hydrogen phosphite 
• 33142-26-6 Diethyl (1-Formyl-1-phenylmethyl)phosphonate 
• 1809-19-4 dibutyl hydrogen phosphite 
• 7436-90-0 2,2-dibromostyrene 
• 5153-67-3 nitrostyrene 
• 100-42-5 styrene 
• 140-10-3 (E)-3-phenylacrylic acid 

Relevant academic research and scientific papers

Copper-mediated cross-coupling of H-phosphonates with vinyliodonium salts: A novel very mild synthesis of 2-arylvinylphosphonates

(Chemical Equation Presented) We report a novel, very mild, highly stereoselective preparation of 2-arylvinylphosphonates at room temperature that involves the copper iodide-mediated cross-coupling of H-phosphonates with vinyliodonium tetrafluoroborates.

Cu(i)/Fe(III)-Catalyzed C-P cross-coupling of styrenes with H-phosphine oxides: A facile and selective synthesis of alkenylphosphine oxides and β-ketophosphonates

Cu(i)/Fe(iii)-Catalyzed phosphorylation and oxyphosphorylation of styrenes with H-phosphonates which can be controlled by varying the reaction temperature are developed. This study offers a new and expedient strategy for the synthesis of useful alkenylphosphine oxides and β-ketophosphonates in satisfactory yields. Moreover, the transformation is proposed to proceed via a radical process and exhibits a broad substrate scope and good functional group tolerance.

Silver-catalyzed synthesis of 2-arylvinylphosphonates by cross-coupling of β-nitrostyrenes with: H -phosphites

An efficient protocol for stereoselective synthesis of 2-arylvinylphosphonates has been developed via AgNO3-catalyzed cross-coupling of β-nitrostyrenes with dialkyl H-phosphites under mild conditions. By losing the nitro group of β-nitrostyrene

Nickel-catalyzed decarboxylative C-P cross-coupling of alkenyl acids with P(O)H compounds

The first nickel-catalyzed decarboxylative C-P coupling of a wide range of alkenyl acids with various P(O)H compounds, especially for H-phosphonates, has been developed, affording a versatile and efficient tool for the preparation of valuable (E)-1-alkeny

Copper-mediated selective cross-coupling of 1,1-dibromo-1-alkenes and heteronucleophiles: Development of general routes to heterosubstituted alkynes and alkenes

Efficient and general procedures for the cross-coupling of 1,1-dibromoalkenes and N-, O-, and P-nucleophiles are reported. Fine-tuning of the reaction conditions allows for either site-selective, double, or alkynylative cross-coupling, therefore providing

Copper-mediated cross-coupling of 1,1-dibromo-1-alkenes with dialkyl phosphites: A convenient synthesis of 1-alkenylphosphonates

An efficient and stereoselective procedure for the preparation of E-1-alkenylphosphonates by copper-mediated cross-coupling between 1,1-dibromo-1-alkenes and dialkyl phosphites is reported. The reaction allows for formal substitution of both bromine atoms

A new synthesis of vinyl phosphonates from α-phenyl β-oxo phosphonates and dialkyl phosphite

Reaction of 1-phenyl-2-oxo phosphonates with dialkyl phosphite sodium salt gave (E) vinyl phosphonates in good yield.