14705-30-7Relevant academic research and scientific papers
CARBONYLATION OF TERTIARY ALKYL HALIDES, SYNTHESIS OF PIVALOYL HALIDES
Brunet, J.-J.,Legars, P.,Peres, Y.,Tkatchenko, I.,Lecolier, S.
, p. 4569 - 4572 (2007/10/02)
The carbonylation of tert-butyl halides in a two-phase system, RSO3H/CCl4, under carbon monoxide pressure affords the corresponding pivaloyl halides in good yields and selectivities.
THE REACTION OF CARBANIONS WITH 2-SUBSTITUTED -2-NITROPROPANES SUBSTITUTION AND DIMERIZATION OCCURRING BY RADICAL CHAIN PROCESSES INVOLVING ELECTRON TRANSFER
Russell, Glen A.,Mudryk, Boguslaw,Ros, Francisco,Jawdosiuk, Mikolaj
, p. 1059 - 1068 (2007/10/02)
The reaction of mono-enolate anions with O2NCMe2X where X=Cl, NO2, p-MePhSO2 yield coupling (RCOCH(R')(CMe2NO2) and enolate dimerization products (RCOCH(R')CH(R')COR) by free radical chain mechanisms involving bimolecular substitution or electron transfer reactions between the enolate anion and the intermediate nitro alkane radical anion (XCMe2NO2(1-)).
