21272-86-6

Basic information

• Product Name: Benzene, 1-methyl-4-[(1-methyl-1-nitroethyl)sulfonyl]-
• CAS NO: 21272-86-6
• Molecular Formula: C10H13NO4S
• Molecular Weight: 243.284
• Mol File: 21272-86-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-4-[(1-methyl-1-nitroethyl)sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-4-[(1-methyl-1-nitroethyl)sulfonyl]-(21272-86-6)
• EPA Substance Registry System: Benzene, 1-methyl-4-[(1-methyl-1-nitroethyl)sulfonyl]-(21272-86-6)

Safety Data

• Hazardous Substances Data: 21272-86-6(Hazardous Substances Data)

Upstream product

• 79-46-9 2-nitropropane 
• 1950-78-3 p-toluenesulfonyl iodide 
• 5447-97-2 2-bromo-2-nitropropane 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 24163-39-1 sodium 2-nitropropane 
• 38590-81-7 2-iodo-2-nitropropane 
• 594-71-8 2-chloro-2-nitro-propane 

Downstream Products

• 14705-30-7 2,2,5-trimethyl-hex-4-en-3-one 
• 51751-71-4 1-methyl-4-(propane-2-sulfonyl)benzene 
• 18598-93-1 α-nitro tert-butyl acetate 
• 3964-18-9 2,3-dimethyl-2,3-dinitrobutane 
• 6802-75-1 diethyl isopropylidenemalonate 
• 34733-55-6 2,3-dimethyl-1,4-diphenyl-butane-1,4-dione 
• 14195-15-4 α-(p-methylbenzenesulfonyl)propiophenone 
• 78706-73-7 2,3-dimethyl-3-nitro-1-phenyl-1-butanone 
• 79-46-9 2-nitropropane 
• 80866-08-6 diethyl 2-nitroisopropylthiophosphonate 
• 27610-88-4 2,2,7,7-tetramethyloctan-3,6-dione 
• 56410-24-3 N,N'-bis(p-toluenesulfonyl)hydroxylamine 
• 52755-34-7 1-methyl-1-nitroethyl p-chlorophenyl sulphide 

Relevant articles and documents

Pathways in the Reactions of Nitronate Ions with Sulphonyl Halides

Primary and tertiary nitronate ions and sulphonyl bromides and iodides rapidly equilibrate with the nitrohalides and sulphinate ion.Products are determined by solvent and by the occurence of cross-equilibrum reactions, some of which have single-electron-transfer mechanism.The reaction of arene-sulphinate and thiolate ions with 1,2-dibromo-2-nitro-1-phenylethane gave E-β-nitrostyrene by Z-philic elimination in both cases, but the more basic thiolate ion also gave, by protophilic elimination, 2-bromo-2-nitro-1-phenylethene.