14710-17-9

Upstream product

• 7647-01-0 hydrogenchloride 
• 14898-67-0 ruthenium trichloride trihydrate 
• 672-66-2 Dimethyl(phenyl)phosphine 
• 14898-67-0 ruthenium trichloride hydrate 

Downstream Products

• 112515-18-1 bis(dimethylphenylphosphine)tris(pentafluorothiophenolato)ruthenium(III) 
• 142417-94-5 RuCl(P(CH₃)2C₆H₅)2C₆H₁₂S₃⁽¹⁺⁾ 
• 105428-90-8 [(P(CH₃)2(C₆H₅))2RuB₁₀H₈(OCH₂CH₃)2] 
• 22860-60-2 {RuCl₂(hydrazine)(dimethylphenylphosphine)3} 
• 22860-49-7 {RuCl₂(methylamine)(dimethylphenylphosphine)3} 
• 68249-91-2 (4-amino-2-imino-4-methylpentane)bis(dimethylphenylphosphine)bis(monothiobenzoato)ruthenium(II) 
• 103498-16-4 6,6,6-(PMe₂Ph)3-nido-6-RuB₉H₁₃ 
• 81704-56-5 bis(dimethylphenylphosphine)bis(monothiobenzoato)ruthenium(II) 
• 22671-11-0 {RuBr₃(C₆H₅(CH₃)2P)3} 
• 22860-60-2 {RuCl₂(N₂H₄)(C₆H₅(CH₃)2P)3} 
• 23329-27-3 {RuCl₂(NH₃)(C₆H₅(CH₃)2P)3} 

Relevant academic research and scientific papers

Structural, Spectroscopic and Redox Studies of mer- (L = PMe2Ph or AsMe2Ph, X = Cl or Br). Crystal Structures of mer- (X = Cl or Br) and (X = Br, E = P or As; X = I, E =As)

The complexes mer- (X = Cl or Br, L = PMe2Ph or AsMe2Ph) have been re-examined and assignments for their UV/VIS spectra proposed.Attempts to prepare analogues with X = I or L = SbR3 have been unsuccessful.Cyclic voltammetry revealed only irreversible oxidation and reduction processes and chemical oxidation with halogens resulted in decomposition to 2-, in contrast to the chemistry of related osmium compounds.The crystal structures of mer- (X = Cl or Br) have been determined and confirm the geometrical isomer formed.Crystal structures were also determined for (X = Br, L = PMe2Ph or AsMe2Ph; X = I, L = AsMe2Ph) obtained by decomposition of mer- in solution, which are the first structurally characterised examples of Ru25+ dimers of this type with bromide or iodide co-ligands.The structures are consistent with a formal Ru-Ru bond order of 1/2.