147159-26-0

Upstream product

• 31469-15-5 1-methoxy-2-methyl-1-trimethylsiloxy-1-propene 
• 7205-91-6 phenylthiomethyl chloride 
• 14002-80-3 Methyl 2,2-dimethyl-3-hydroxypropionate 
• 882-33-7 diphenyldisulfane 

Downstream Products

• 38434-99-0 3-Benzenesulfonyl-2,2-dimethyl-propionic acid methyl ester 
• 20967-51-5 3-(phenylthio)-2,2-dimethylpropanal 
• 718620-98-5 (E)-1-Benzenesulfonyl-6-[(4S,6R)-6-((R)-1-benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-2,2-dimethyl-hex-4-en-3-one 
• 1053256-74-8 1-Benzenesulfonyl-6-[(4S,6R)-6-((R)-1-hydroxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-2,2-dimethyl-hexan-3-one 
• 501677-42-5 (S)-6-(2-Benzenesulfonyl-1,1-dimethyl-ethyl)-2-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-ylmethyl)-3,4-dihydro-2H-pyran 
• 380579-43-1 (4-benzenesulfonyl-3,3-dimethyl-2-oxo-butyl)-phosphonic acid dimethyl ester 
• 51916-36-0 2-Phenylthiomethyl-2-methyl-1-propanol 

Relevant academic research and scientific papers

Concise formal synthesis of the bryostatin southern hemisphere (C17-C27)

An efficient synthesis of Hale and co-workers' C17-C27 bryostatin southern hemisphere intermediate has been accomplished in six steps and 33% overall yield from (R)-2-(benzyloxy)propanal. The synthesis features a one-pot DIBALH/HWE ester homologation as w

An approach to the C(17)-C(24) fragment of bryostatins: Applications of stereoselective trisubstituted alkene formation by palladium(0) catalysed coupling of enol acetates and vinylic bromides

The enol acetate 26 couples stereospecifically with the vinylic bromides 25 and 29 in the presence of tributyltin methoxide and a catalytic amount of dichlorobis(tri-o-tolylphosphine)palladium to give the βγ-unsaturated ketones 27 and 30 with retention of