147189-69-3Relevant academic research and scientific papers
Diastereoselectivity of the thio-Claisen rearrangement of acyclic precursors bearing a chiral centre adjacent to carbon 6
Desert, Stephane,Metzner, Patrick
, p. 10327 - 10338 (2007/10/02)
A number of chiral allylic alcohols have been prepared and submitted to a Mitsunobu reaction with dithioacetic acid. Allyl dithioesters were deprotonated by LDA at -30°C and resulting enethiolates were quenched with iodomethane to afford quantitatively S-
