116525-11-2Relevant academic research and scientific papers
Diastereoselectivity of the thio-Claisen rearrangement of acyclic precursors bearing a chiral centre adjacent to carbon 6
Desert, Stephane,Metzner, Patrick
, p. 10327 - 10338 (2007/10/02)
A number of chiral allylic alcohols have been prepared and submitted to a Mitsunobu reaction with dithioacetic acid. Allyl dithioesters were deprotonated by LDA at -30°C and resulting enethiolates were quenched with iodomethane to afford quantitatively S-
CATALYTIC OSMYLATION OF ELECTRON POOR ALLYLIC ALCOHOLS AND ETHERS. A SYNTHETIC APPROACH TO BRANCHED CHAIN SUGARS
Bernardi, Anna,Cardani, Silvia,Scolastico, Carlo,Villa, Roberto
, p. 491 - 502 (2007/10/02)
The catalytic osmylation of electron-poor allylic ethers and alcohols was studied.In the case of γ-alkoxy E-enoates reaction selectivity was found to range from 2:1 to 8:1 in favor of the arabino (2,3-syn - 3,4-anti) product, regardless of the double bond
