147441-61-0

Basic information

• Product Name: 1,3-Dioxolane, 2,2-dimethyl-4-phenyl-, (4R)-
• CAS NO: 147441-61-0
• Molecular Formula: C11H14O2
• Molecular Weight: 178.231
• Mol File: 147441-61-0.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 1,3-Dioxolane, 2,2-dimethyl-4-phenyl-, (4R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dioxolane, 2,2-dimethyl-4-phenyl-, (4R)-(147441-61-0)
• EPA Substance Registry System: 1,3-Dioxolane, 2,2-dimethyl-4-phenyl-, (4R)-(147441-61-0)

Safety Data

• Hazardous Substances Data: 147441-61-0(Hazardous Substances Data)

Usage

Physical state

Clear, colorless liquid at room temperature

Usage

Different sources of media describe the Usage of 147441-61-0 differently. You can refer to the following data:
1. Precursor in the synthesis of various pharmaceuticals and organic compounds
2. Solvent in some industrial processes

Stereochemistry

(4R) designation indicates the orientation of substituent groups around the chiral center

Application

Primarily used in research and industrial applications

Safety

Should be handled and stored with appropriate safety measures due to potential hazards

Upstream product

• 93-56-1 phenylethane 1,2-diol 
• 67-64-1 acetone 
• 20780-53-4 (R)-Styrene oxide 
• 100-42-5 styrene 
• 77-76-9 2,2-dimethoxy-propane 
• 1169707-70-3 (S,Z)-1-phenylbut-2-ene-1,4-diol 
• 16939-57-4 (E)-buta-1,3-dienylbenzene 
• 16355-00-3 (R)-1-phenyl-1,2-ethanediol 
• 96-09-3 styrene oxide 

Downstream Products

• 16355-00-3 (R)-1-phenyl-1,2-ethanediol 

Relevant articles and documents

Cu(OTf)2-catalyzed selective opening of aryl and vinyl epoxides with carbonyl compounds to give 1,3-dioxolanes

Copper(II) triflate catalyzes the ring-opening of aryl- and vinyl-substituted epoxides with various carbonyl compounds to furnish 1,3-dioxolanes under mild conditions. Alkyl- and alkoxycarbonyl-substituted epoxides remain unchanged under reaction conditio

Carbohydrate-Catalyzed Enantioselective Alkene Diboration: Enhanced Reactivity of 1,2-Bonded Diboron Complexes

Catalytic enantioselective diboration of alkenes is accomplished with readily available carbohydrate-derived catalysts. Mechanistic experiments suggest the intermediacy of 1,2-bonded diboronates.

Modular monodentate oxaphospholane ligands: Utility in highly efficient and enantioselective 1,4-diboration of 1,3-dienes

Tune it up! Tunable, chiral, monodentate oxaphospholane ligands (termed OxaPhos) are highly effective in the Pt-catalyzed title reaction, providing the 1,4-addition products in enantiomer ratios approaching 99:1 (see scheme). In the presence of enantiomerically pure cis-iBu-OxaPhos, a catalyst loading of only 0.02 mol% [Pt(dba)3] was sufficient for effective reaction. pin=pinacolato, dba=dibenzylideneacetone.