147492-76-0Relevant articles and documents
Zinc-Catalysed Hydroboration of Terminal and Internal Alkynes
Mandal, Souvik,Mandal, Sayantan,Geetharani
, p. 4553 - 4556 (2019/08/20)
A regioselective hydroboration of alkynes has been developed by using commercially available zinc triflate as a catalyst, in the presence of catalytic amount of NaBHEt3. The reaction tolerates a wide range of terminal alkynes having several synthetically useful functional groups and proceeds regioselectively to furnish hydroborated products in moderate to excellent yields. This system shows moderate chemoselectivity towards terminal C≡C bond over terminal and internal C=C bond and internal C≡C bond.
Molecular daisy chains: Synthesis and aggregation studies of an amphiphilic molecular rod
Rotzler, Juergen,Drayss, Sylvie,Hampe, Oliver,Haeussinger, Daniel,Mayor, Marcel
, p. 2089 - 2101 (2013/04/10)
A water-soluble cyclophane as the loop subunit, monofunctionalized with a molecular rod, has been synthesized to introduce a new binding motif for mechanically interlinked oligomers. It has been demonstrated that this hermaphroditic compound forms [c2]dai
Fluoro-substituted phenyleneethynylenes: Acetylenic n-type organic semiconductors
Matsuo, Daisuke,Yang, Xin,Hamada, Akiko,Morimoto, Kyo,Kato, Takuji,Yahiro, Masayuki,Adachi, Chihaya,Orita, Akihiro,Otera, Junzo
, p. 1300 - 1302 (2011/02/17)
Fluoro-substituted phenyleneethynylenes are synthesized by Sonogashira coupling and acetylide-nucleophilic substitution of fluorobenzenes. Fluoro-substitution of benzenes enables deep LUMO potential, and CF 3-substitution provides high electron