14753-87-8Relevant academic research and scientific papers
Ferrocenyl quinone methides as strong antiproliferative agents: Formation by metabolic and chemical oxidation of ferrocenyl phenols
Hamels, Didier,Dansette, Patrick M.,Hillard, Elizabeth A.,Top, Siden,Vessieres, Anne,Herson, Patrick,Jaouen, Gerard,Mansuy, Daniel
, p. 9124 - 9126 (2009)
Ferrocenyl quinone methides, potentially cytotoxic species, are formed by metabolic and chemical oxidation of ferrocenyl phenols (see scheme). These species display strong antiproliferative properties.
Highly Selective and Divergent Acyl and Aryl Cross-Couplings of Amides via Ir-Catalyzed C-H Borylation/N-C(O) Activation
Gao, Pengcheng,Szostak, Michal
supporting information, p. 6010 - 6015 (2020/07/30)
Herein, we demonstrate that amides can be readily coupled with nonactivated arenes via sequential Ir-catalyzed C-H borylation/N-C(O) activation. This methodology provides facile access to biaryl ketones and biaryls by the sterically controlled Ir-catalyzed C-H borylation and divergent acyl and decarbonylative amide N-C(O) and C-C activation. The methodology diverts the traditional acylation and arylation regioselectivity, allowing us to directly utilize readily available arenes and amides to produce valuable ketone and biaryl motifs.
Kinetics and Mechanism of the Titanium Tetrachloride-catalysed Cyclotrimerisation of Aryl Cyanates
Cunningham, Ian D.,Brownhill, Andrew,Hamerton, Ian,Howlin, Brendan J.
, p. 1937 - 1944 (2007/10/02)
Aryl cyanates are converted cleanly at 25 deg C to 1,3,5-triazines by catalytic amounts of titanium tetrachloride in dichloromethane.Based on IR spectroscopic, kinetic and product analysis, a mechanism is proposed involving rate -limiting nucleophilic att
