14758-41-9Relevant academic research and scientific papers
Selectivities in the Reactions of Alkyl-, Aryl- and Heterosubstituted Organotitanium Compounds
Weidmann, Beat,Widler, Leo,Olivero, Alan G.,Maycock, Christopher D.,Seebach, Dieter
, p. 357 - 361 (2007/10/02)
Solutions of the title compounds R-Ti(OR')3 (1) are generally available from organolithium (or magnesium) derivatives according to equation 1.It is shown (table 1) that some heterosubstituted organotitanium compounds are more stable thermally than their lithium counterparts.The reagents 1 are highly selective carbonylophiles (Tables 1 and 2), their reactivity can be modified by variation of the R'O-group (Table 3) and with the chiral (S)-2-methyl-1-butoxy group an enantioselective addition can be achieved.
New synthetic routes to vinyl sulfides, ketene thioacetals and their seleno analogues from carbonyl compounds
Denis,Desauvage,Hevesi,Krief
, p. 4009 - 4012 (2007/10/02)
Title compounds have been prepared from carbonyl compounds by formal removal of hydroxyl and sulfenyl or hydroxyl and selenyl moieties from the corresponding functionalized β-hydroxysulfides or β-hydroxyselenides.
